Crosslinked organic??????inorganic hybrid chitosan membranes for pervaporation dehydration of isopropanol??????water mixtures with a long-term stability
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- 作者：Liu ; Ying-Ling ; Su ; Yu-Huei ; Lee ; Kuir-Rain ; Lai ; Juin-Yih
- 关键词：Chitosan ; Pervaporation ; Crosslinked membrane ; Isopropanol– ; water separation
- 刊名：Journal of Membrane Science
- 出版年：2005
- 出版时间：April 1, 2005
- 年：2005
- 卷：251
- 期：1-2
- 页码：233-238
- 全文大小：303 K
文摘
Crosslinked organic–inorganic hybrid chitosan membranes were obtained from blending chitosan and γ-(glycidyloxypropyl)trimethoxysilane (GPTMS) in acetic acid aqueous solution. The hydrophilicity of the modified membranes was not significantly decreased, so as to result in good permselectivity and high permeation flux in pervaporative dehydration on a 70 wt. % isopropanol–water (IPA–H2O) solution. A flux of 1730 g/(m2 h) and a separation factor of 694 were found with the chitosan membrane containing 5 wt. % GPTMS. Both of the crosslinked and organic–inorganic hybrid structures contribute to stabilize the membranes to maintain the performance of the membranes in a 140 days long-term operation.