The self-associating behavior of NH3 and ND3 in liquid xenon
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- 作者：Liene I. De Beuckeleer ; Wouter A. Herrebout ; wouter.herrebout@uantwerpen.be" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ammonia ; Ammonia-d3 ; Self-association ; Cryosolutions ; Liquid xenon ; Infrared spectroscopy ; Least-squares fitting ; Monomer ; Dimer ; Trimer ; Tetramer
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 August 2016
- 年：2016
- 卷：1118
- 期：Complete
- 页码：34-41
- 全文大小：1198 K
文摘
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Self-association of NH3 and ND3 is observed in the infrared spectra of cryosolutions with liquid xenon.
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Least-squares fitting of polynomials to the data allows us to resolve spectral regions with overlapping absorbance bands.
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Least-squares fitting of polynomials yields accurate information on monomer and oligomer species present in the solutions.
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The least-squares fitting method shows an added value towards other methods often used.