PEM fuel cell electrocatalysts based on transition metal macrocyclic compounds
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- 作者：Yuyu Liua ; d ; yuyu_liu2004@hotmail.com" class="auth_mail" title="E-mail the corresponding author ; liu@mail.kankyo.tohoku.ac.jp" class="auth_mail" title="E-mail the corresponding author ; Xiuping Yuea ; Kaixi Lib ; likx@sxicc.ac.cn" class="auth_mail" title="E-mail the corresponding author ; Jinli Qiaoc ; qiaojl@dhu.edu.cn" class="auth_mail" title="E-mail the corresponding author ; David P. Wilkinsone ; Jiujun Zhangf ; jiujun.zhang@nrc.gc.ca" class="auth_mail" title="E-mail the corresponding author
- 关键词：APFP ; (p-aminophenyl)-5 ; 10 ; 15 ; 20(pentafluorophenyl)-porphyrin ; CV ; cyclic voltammetry ; CNT ; carbon nanotube ; CoPP(s) ; Cobalt porphyrin(s) ; DCM ; dichloromethane ; DMSO ; dimethylsulfoxide ; DFT ; density functional theory ; DPX ; 4 ; 5-bis[5-(2 ; 8 ; 13 ; 17-tetraethyl-3 ; 7 ; 12 ; 18-tetramethylporphyrinyl)]-9 ; 9-dimethylxanthene ; DWCNT ; double-walled CNT ; ERGO ; electrochemical reduced graphene oxide ; EDX ; energy dispersive X-ray (spectroscope) ; FePP(s) ; iron porphyrin(s) ; GCE ; glassy carbon electrode ; GO ; graphene
- 刊名：Coordination Chemistry Reviews
- 出版年：2016
- 出版时间：15 May 2016
- 年：2016
- 卷：315
- 期：Complete
- 页码：153-177
- 全文大小：8208 K
文摘
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The paper provides an overview of transition metal macrocyclic (TMM) complex-based electrocatalysts used in ORRs in PEMFCs.
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Performances of TMM catalysts, including both ORR activity rates and stabilities, are discussed.
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The effects of different types and natures of metals, macrocyclic ligands, and so on are analyzed and reviewed.
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Required improvements of TMM catalysts in ORR activity, stability and commercial viability are identified.
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Potential research directions to overcome current challenges are suggested.