Solubility of α-glycine in water with additives at a temperature range of (293.15-343.15) K: Experimental data and results of thermodynamic modeling

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• 作者：Hua Sun^a ; ^b ; Lu Wang^a ; Baoshu Liu^a ; ^b ; ^{liubs99@163.com}
• 关键词：Glycine ; Solubility ; Additives ; Thermodynamic model
• 刊名：Fluid Phase Equilibria
• 出版年：2017
• 出版时间：25 February 2017
• 年：2017
• 卷：434
• 期：Complete
• 页码：167-175
• 全文大小：1290 K
• 卷排序：434

文摘

The solubility of α-glycine in water with different additives (sodium nitrate, ammonium nitrate, ammonium sulfate, and ammonium chloride) was measured under atmospheric pressure across the temperature range of (293.15–343.15) K at intervals of 10.00 K using a dynamic laser method. Solubility was found to increase with increasing temperature and additive level. The experimental data were correlated with the modified Apelblat model, nonrandom two-liquid model (NRTL), and λh model. The R2 of the fitting regression indicated good applicability of these models to the glycine solubility data in the studied systems (R2 > 0.99). Apparent standard enthalpy, entropy, and Gibbs free energy changes of the solution were calculated based on the van't Hoff equation to elucidate the dissolution mechanism. The results showed that the dissolving process of glycine was endothermic, and the main dissolution driving force contributor was enthalpy in all the additive + water systems studied. By means of enthalpy-entropy compensation analysis, a non linear ΔHsolΘ versus ΔGsolΘ enthalpy-entropy compensation plot with positive and negative slopes was obtained for the systems studied. The evaluated values of HE showed that the mixing process of α-glycine in all the systems studied was exothermic.