One-pot conversion of cyclohexanol to ɛ-caprolactam using a multifunctional Na₂WO₄-acidic ionic liquid catalytic system

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• 作者：Hefang Wang ; Liyuan Jia ; Rongbin Hu ; Meidan Gao ; Yanji Wang ; ^{yjwang@hebut.edu.cn}
• 关键词：Cyclohexanol ; ɛ-Caprolactam ; One-pot synthesis ; Acidic ionic liquid ; Cyclohexanone oxime
• 刊名：Chinese Journal of Catalysis
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：38
• 期：1
• 页码：58-64
• 全文大小：529 K
• 卷排序：38

文摘

Na2WO4-acidic ionic liquid was used as a simple, ecofriendly, recyclable and efficient catalytic system for the one-pot conversion of cyclohexanol to ɛ-caprolactam. The effect of the structure of the ionic liquid on the catalytic activity of this system was investigated, and the results revealed that sulfonic acid-functionalized ionic liquids with HSO4− as an anion gave the best results. The highly efficient performance of this catalyst system was attributed to the phase-transfer behavior of the cation of the ionic liquid, the improved coordination of the substrate to bisperoxotungstate during the oxidation reaction, and the stabilization of the intermediate formed during the Beckmann rearrangement.