Visible light-driven photophysics and photochemistry of water-soluble metalloporphyrins
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- 作者：Ottó ; Horvá ; tha ; otto@mk.uni-pannon.hu" class="auth_mail" title="E-mail the corresponding author ; Zsolt Valicseka ; Melinda A. Fodora ; Má ; té ; M. Majora ; Muhammad Imrana ; Gü ; nter Gramppb ; Alexander Wankmü ; llerb
- 关键词：Metalloporphyrins ; Photochemistry ; Out-of-plane complexes ; In-plane complexes ; Photocatalysis ; Lanthanide ions
- 刊名：Coordination Chemistry Reviews
- 出版年：2016
- 出版时间：15 October 2016
- 年：2016
- 卷：325
- 期：Complete
- 页码：59-66
- 全文大小：1917 K
文摘
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Cationic Mn(III), Co(III) and Ni(II) porphyrins show characteristic fluorescence.
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Their long-lived triplet excited states play key roles in photocatalytic systems.
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Anionic Ln(III) mono- and bisporphyrins exhibit similar photoinduced properties.
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Their photolysis at the Soret-band produces a radical type intermediate.
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However, during their irradiation at the Q-bands, a stable photoproduct appears.