Octa(3-mercaptopropyl)octasilsesquioxane - A reactive nanocube of unique self-assembled packing morphology
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- 作者：Anna Kowalewskaa ; anko@cbmm.lodz.pl" class="auth_mail" title="E-mail the corresponding author ; Maria Nowackaa ; mnowacka@cbmm.lodz.pl" class="auth_mail" title="E-mail the corresponding author ; Waldemar Maniukiewiczb ; waldemar.maniukiewicz@p.lodz.pl" class="auth_mail" title="E-mail the corresponding author
- 关键词：Silsesquioxane ; Mercaptopropyl ; Self-catalytic reaction ; Rod-like molecule ; Mesomorphic transitions
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 May 2016
- 年：2016
- 卷：810
- 期：Complete
- 页码：15-24
- 全文大小：2033 K
文摘
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The role of thiol moieties in the synthesis of octa(3-mercaptopropyl)octasilsesquioxane is elucidated.
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Rod-like geometry of the molecule and self-assembling of side groups affect crystalline packing morphology.
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Solid-solid and solid-liquid mesomorphic transitions were observed for crystalline octa(3-mercaptopropyl)octasilsesquioxane.