Polyethylene like polymers. Aliphatic polyesters of dodecanedioic acid: 1. Synthesis and properties

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• 作者：Barbiroli ; Giancarlo ; Lorenzetti ; Cesare ; Berti ; Corrado ; Fiorini ; Maurizio ; Manaresi ; Piero
• 关键词：Aliphatic polyesters ; 1 ; 12-dodecanedioc acid ; Chemical recycle
• 刊名：European Polymer Journal
• 出版年：2003
• 出版时间：April, 2003
• 年：2003
• 卷：39
• 期：4
• 页码：655-661
• 全文大小：256 K

文摘

A series of aliphatic polyesters has been synthesized starting from 1,12-dodecanedioic acid and aliphatic diols, bearing from 2 to 12 carbon atoms. These polymers, which were fully characterized in terms of chemical structure, molecular weight and thermal behaviour, were obtained as crystalline materials with melting points ranging from 70 to 90 °C and with a relatively high molecular weight. All the monomers used can be obtained from biomasses, as a consequence these materials can be an interesting alternative to synthetic polymers produced from petrochemical processes based on nonrenewable resources.