A non-interpenetrating 3D porous metal-organic framework (MOF) holding rutile-type topology containing Cu₄ secondary building units

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• 作者：Gong-ming Sun ; Xue-feng Feng ; Hai-xiao Huang ; Zhen-wei Liao ; Yu-mei Song ; Xiao-zhao Tian ; Shu-juan Liu ; Feng Luo ; ^{ecitluofeng@163.com}
• 关键词：Porous MOFs ; Cu4 secondary building units ; Rutile ; Solvo(hydro)thermal method
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 出版时间：February, 2012
• 年：2012
• 卷：16
• 期：Complete
• 页码：43-46
• 全文大小：777 K

文摘

In this work, we obtained a rarely three-dimensional porous Cu(II) MOF, namely [Cu₂(BTC)(OH)(Me₂NH)?#xA0;2H₂O ?#xA0;DMF]_n (Me₂NH¡ªdimethylamine, [BTC^{3 ?/sup>?,3,5-benzenetricarboxylate, DMF¡ªN,N?dimethylformamide], by solvo(hydro)thermal method. This polymer was characterized by single-crystal X-ray diffraction, EA, and thermogravimetry analysis. The outstanding structural feature of it is the coordination of Me₂NH¡ªa hydrolysate from DMF, and the non-interpenetrating porous rutile net. Further, based on the investigation of literatures, we also discussed the architectonics involving common Cu₄ secondary building unit (SBU) in detail.}