Thermodynamic studies of the ionic liquid 1-hexyl-3-methylimidazolium chloride [C₆mim][Cl] in polyethylene glycol aqueous solutions

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• 作者：Rahmat Sadeghi ; ^{rahsadeghi@yahoo.com} ; ^{rsadeghi@uok.ac.ir} ; Nosaibah Ebrahimi ; Adibeh Mahdavi
• 关键词：Ionic liquid ; 1-Hexyl-3-methylimidazolium chloride ; Isopiestic ; Vapour pressure osmometery ; Water activity ; Polyethylene glycol
• 刊名：Journal of Chemical Thermodynamics
• 出版年：2012
• 出版时间：April 2012
• 年：2012
• 卷：47
• 期：Complete
• 页码：48-55
• 全文大小：377 K

文摘

Vapour pressure osmometery (VPO) measurements at T = 308.15 K for {[C₆mim][Cl] + water}, {[C₆mim][Cl] + (0.005, 0.0155, and 0.0263) mol ¡¤ kg^? PEG2000 + water} and {[C₆mim][Cl] + (0.0017, 0.0052, and 0.0088) mol ¡¤ kg^? PEG6000 + water} systems and isopiestic measurements at T = 298.15 K for {[C₆mim][Cl] + PEG2000 + water} and {[C₆mim][Cl] + PEG6000 + water} systems have been carried out. The VPO measurements were carried out at very low concentrations of PEG and from which the values of the water activities, osmotic coefficients, vapour pressure and activity coefficients were obtained. The data obtained from the VPO method show that over the whole concentration range of the ionic liquid (IL), the activity coefficients of [C₆mim][Cl] in the presence of PEG2000 are increased. Although, at high IL concentrations, the values of the activity coefficient of [C₆mim][Cl] in the presence of PEG6000 are also increased, however for low concentrations of IL the values of the activity coefficient of [C₆mim][Cl] in pure water are larger than those in aqueous PEG6000 solutions. For a known IL concentration, the values of water activity coefficient for the binary {[C₆mim][Cl] + water} system are larger than those for the ternary {[C₆mim][Cl] + PEG + water} systems and decrease by increasing the concentration of PEG or decreasing the molar mass of PEG. The constant water activity lines of the all ternary systems obtained from the isopiestic method show positive deviation from the linear isopiestic relation (Zdanovskii-Stokes-Robinson rule) derived using the semi-ideal hydration model. The results have been interpreted in terms of the solute-water and solute-solute interactions.