刊名:Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
出版年:2017
出版时间:5 March 2017
年:2017
卷:174
期:Complete
页码:130-137
全文大小:1115 K
卷排序:174
文摘
A general assay of catalytically relevant reactivities of iron complexes is presented. Iron pyridyl complexes with cis open coordination sites are the most reactive. In the presence of H2O2, iron complexes quickly transition to a single intermediate. Some iron complex reactivities reflect a sensitivity to different peroxides.