Relation among optical, thermal and thermo-optical properties and niobium concentration in tellurite glasses

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• 作者：J.C.S. Moraes ; J.A. Nardi ; S.M. Sidel ; B.G. Mantovani ; K. Yukimitu ; V.C.S. Reynoso ; L.F. Malmonge ; N. Ghofraniha ; G. Ruocco ; L.H.C. Andrade ; S.M. Lima
• 关键词：Tellurite glasses ; Optical properties ; Thermal properties ; Thermo-optical properties ; Raman spectroscopy
• 刊名：Journal of Non-Crystalline Solids
• 出版年：2010
• 出版时间：1 September 2010
• 年：2010
• 卷：356
• 期：41-42
• 页码：2146-2150
• 全文大小：430 K

文摘

In this work, optical, thermal, thermo-optical and spectroscopic properties of the 80TeO₂-(20 − x)Li₂O-xNb₂O₅ (x = 5, 10 and 15 mol % ) glasses were investigated by using the thermal lens spectrometry, X-Ray diffraction, Raman spectroscopy, modulated differential scanning calorimetry and Brewster angle method. The influence of Nb₂O₅ in the glass structure was interpreted by the thermal diffusivity, specific heat, thermal conductivity, temperature coefficient of the optical path length, refractive index and band gap energy. The calculated optical basicity and polarizability allowed bettering understanding the obtained results, reinforcing the assumption on the glass structural change.