Vibronic emission spectrum of 2-chloro-6-fluorobenzyl radical produced in corona discharge
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- 作者：Young Wook Yoon ; Sang Youl Chae ; Manho Lim ; Sang Kuk Lee ; sklee@pusan.ac.kr" class="auth_mail" title="E-mail the corresponding author ; sanglee52@daum.net" class="auth_mail" title="E-mail the corresponding author
- 刊名：Chemical Physics Letters
- 出版年：2015
- 出版时间：16 September 2015
- 年：2015
- 卷：637
- 期：Complete
- 页码：148-152
- 全文大小：461 K
文摘
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We observe the vibronic emission spectrum of the 2-chloro-6-fluorobenzyl radical.
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We determine the electronic transition energy and vibrational mode energies.
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We discuss the substituent effect of two halogens on electronic transition energy.
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We propose a mechanism for radical formation by corona discharge.