Displacement of Cl substituent in chlorofluorotoluene in corona discharge
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- 作者：Sang Youl Chae ; Manho Lim ; Sang Kuk Lee ; sklee@pusan.ac.kr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Displacement mechanism ; Spectroscopy ; Corona discharge ; 2-Chloro-6-fluorobenzyl radical ; 2-Chloro-6-fluorotoluene ; Bond dissociation energy
- 刊名：Chemical Physics Letters
- 出版年：2016
- 出版时间：1 November 2016
- 年：2016
- 卷：664
- 期：Complete
- 页码：242-245
- 全文大小：347 K
文摘
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Dissociative products in corona discharge were observed via vibronic emission spectrum.
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We find the difference in products between 2-chloro-6-fluorotoluene and 2-chloro-6-fluorobenzyl chloride.
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We discuss the difference in terms of bond dissociation energies.
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We propose a mechanism for dissociative process of precursors in corona discharge.