Thermodynamic models of the adsorption and desorption of molecular oxygen at the UV and blue emitting centers in mesoporous silica under variable oxygen pressure

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• 作者：Carlo M. Carbonaro ; ^{cm.carbonaro@dsf.unica.it} ; Marcello Salis ; Riccardo Corpino ; Daniele Chiriu ; Luigi Stagi ; Giovanni Serra ; Andrea Bosin ; Pier Carlo Ricci
• 关键词：Mesostructured silica ; Thermodynamic models ; Adsorption/desorption of oxygen ; Luminescence
• 刊名：Microporous and Mesoporous Materials
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：239
• 期：Complete
• 页码：371-380
• 全文大小：1389 K
• 卷排序：239

文摘

Analysis of adsorption and desorption of molecular oxygen upon porous silica defects emitting in the blue and UV range. Thermodynamic models to explain the recorded kinetic. Density functional theory calculations to support the thermodynamic models.