Specific salt effects on the hydrolysis reaction rate of tropolone tosylate in binary MeCN-H2O media containing n-Bu4NOH
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- 作者：Leta Danno Bayissa ; Masashi Hojo ; mhojo@kochi-u.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydrolysis rate constant ; Bulk water structure ; Nucleophilicity ; Coordination ability ; Apparent pH values ; Kinetics
- 刊名：Journal of Molecular Liquids
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：215
- 期：Complete
- 页码：293-301
- 全文大小：505 K
文摘
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The change in the hydrolysis reaction rate in binary MeCN–H2O media
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The coordination abilities of cations from the added salts with the leaving group (tropolonate ion)
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Interactions of metal ions with the prominent nucleophile, the OH− ion
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Changes in activities of H2O/OH− with respect to the added salts and/or MeCN contents