Effect of preparation routes on the catalytic activity over SmFeO₃ oxide

详细信息    查看全文

• 作者：Masami Mori ; Yuji Iwamoto ; Makiko Asamoto ; Yoshiteru Itagaki ; Hidenori Yahiro ; Yoshihiko Sadaoka ; Satoko Takase ; Youichi Shimizu ; Masayoshi Yuasa ; Kengo Shimanoe ; Hajime Kusaba ; Yasutake Teraoka
• 关键词：Preparation of perovskite-type oxide ; SmFeO₃ ; Catalytic activity ; CO oxidation ; XPS
• 刊名：Catalysis Today
• 出版年：2008
• 出版时间：15 December 2008
• 年：2008
• 卷：139
• 期：1-2
• 页码：125-129
• 全文大小：932 K

文摘

The perovskite-type SmFeO₃ powders were prepared by the four different methods, named decomposition method of heteronuclear cyano complexes (CN), polymer precursor method (PP), reverse micelle method (RM) and reverse homogenous precipitation method (RHP), and their catalytic activities were evaluated with a CO oxidation reaction. The surface areas and the surface chemical compositions of Sm, Fe, O and C were strongly dependent on the preparation methods and calcination temperatures. On the basis of such the characteristics on the surface the factors controlling the catalytic activity are discussed.