Highly selective hydrogenation of quinolines promoted by recyclable polymer supported palladium nanoparticles under mild conditions in aqueous medium
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- 作者：Maria Michela Dell&rsquo ; Annaa ; mariamichela.dellanna@poliba.it" class="auth_mail ; mm.dellanna@poliba.it" class="auth_mail ; Vito Filippo Capodiferroc ; Matilda Malia ; Daniela Mannod ; Pietro Cotugnoe ; Antonio Monopolie ; Piero Mastrorillia ; b
- 关键词：Water solvent ; Quinoline hydrogenation ; Polymer supported Pd nanoparticles ; Recyclable catalyst
- 刊名：Applied Catalysis A: General
- 出版年：5 July 2014
- 年：2014
- 卷：481
- 期：Complete
- 页码：89-95
- 全文大小：1589 K
文摘
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Polymer supported Pd catalyst (Pd-pol) promoted the quinoline hydrogenation.
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Pd-pol was active under mild conditions in aqueous medium.
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The catalyst could be reused at least nine times without loss of activity.
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Pd leaching did not occur.
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The in situ formed supported Pd nanoparticles were the true active species.