Insights into the separation performance of MOFs by high-performance liquid chromatography and in-depth modelling
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- 作者：Weiwei Qin ; Martin E. Silvestre ; Gerald Brenner-Weiss ; Zhengbang Wang ; Sophia Schmitt ; Jonas Hü ; bner ; Matthias Franzreb ; matthias.franzreb@kit.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Metal&ndash ; organic framework ; Liquid chromatography ; Separation ; Simulation ; Core&ndash ; shell
- 刊名：Separation and Purification Technology
- 出版年：2015
- 出版时间：17 December 2015
- 年：2015
- 卷：156
- 期：part_P2
- 页码：249-258
- 全文大小：2164 K
文摘
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Highly ordered MOF core–shell structures are introduced as chromatography sorbents.
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The sorbents are fabricated by a liquid phase epitaxy process in a layer-by-layer fashion.
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Columns filled with these sorbents achieve separation of mixtures of phenol derivatives.
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We report in-depth simulation of the chromatographic performance of MOF materials.
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We discuss strengths and weaknesses of MOFs for analytical and preparative separations.