Synthesis, characterization and reactivity of vanadium, chromium, and manganese PNP pincer complexes
文摘
The synthesis and characterization of new V, Cr, and Mn PNP pincer is reported. Fragmentation of all complexes is investigated by means of ESI-MS. Structures of complexes were determined by X-ray single crystal analyses. These complexes catalyze the oxidative homo-coupling of aryl Grignard reagents.