Comment on the papers L. Chen et al., “Densities, viscosities, and excess properties of binary mixtures of two imidazolide anion functionalized ionic liquids with water at T = (293.15-313.15) K” and Z.P. McAtee et al., “Density, viscosity and excess properties in the trihexyltetradecylphosphonium chloride ionic liquid/met
文摘
The relative viscosity of mixture, ηr, was put forward. ηr is well related to the corresponding excess Gibbs free energy of activation for viscous flow. According to Eyring’s equation, a new relationship was set up between ΔG≠E and viscosity of mixture.