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• 作者：Fawcett ; John ; Kemmitt ; Raymond D.W. ; Russell ; David R. ; Serindag ; Osman
• 关键词：Palladium ; Platinum ; Aminomethylphosphines ; Dibenzylideneacetone ; Crystal structure
• 刊名：Journal of Organometallic Chemistry
• 出版年：1995
• 出版时间：January 25, 1995
• 年：1995
• 卷：486
• 期：1-2
• 页码：171-176
• 全文大小：556 K

文摘

Tris(dibenzylideneacetone)dipalladium and bis(dibenzylideneacetone)platinum react with N,N -bis(dicyclohexylphosphinomethyl)methylamine, (Cy₂PCH₂)₂NMe (Cy = cyclohexyl), and with N, N-bis(diphenylphosphinomethyl)methylamine, (Ph₂PCH₂)₂NMe (Ph = phenyl), to give the complexes [M(dba){(R₂PCH₂)₂NMe}] (M = Pd or Pt, dba = dibenzylideneacetone), R = Cy or Ph. Thezerovalent platinum complex [Pt(PPh₃){(Cy₂PCH₂)₂NMe}] can be obtained by hydrazine hydrate reduction of a mixture of [PtCl₂{(Cy₂PCH₂)₂NMe}] and triphenylphosphine or one of cis-[PtCl₂(PPh₃)₂] and (Cy₂PCH₂)₂NMe. The crystal structure of [Pd(dba){(Cy₂PCH₂)₂NMe}] has been determined and some reactions of the complexes are reported.