One-step oxidehydration of glycerol to acrylic acid using ETS-10-like vanadosilicates
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- 作者：Alex Silva Paulaa ; Luiz Gustavo Possatob ; Davi Rubinho Rateroa ; Janine Controa ; Keren Keinan-Adamskyc ; Ricardo Reis Soaresd ; Gil Goobesc ; Leandro Martinsb ; José ; G. Nerya ; nery@ibilce.unesp.br" class="auth_mail" title="E-mail the corresponding author
- 关键词：Vanadosilicates ; Glycerol ; Oxidehydration reactions ; Acrylic acid ; Mars-van Krevelen mechanism
- 刊名：Microporous and Mesoporous Materials
- 出版年：2016
- 出版时间：15 September 2016
- 年：2016
- 卷：232
- 期：Complete
- 页码：151-160
- 全文大小：2251 K
文摘
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ETS-10 like vanadosilicates were synthesized and characterized by several techniques.
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Catalysts were used for glycerol conversion into acrylic acid in one step.
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High glycerol conversion (93.6%) and acrylic acid selectivity (85.4%) were obtained.