Study on photocurrent of bilayers photoanodes using different combination of WO₃ and Fe₂O₃

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• 作者：Amir Memar ; Wan Ramli Wan Daud ; Soraya Hosseini ; Ehsan Eftekhari ; Lorna Jeffery Minggu
• 关键词：Photoelectrolysis ; Water splitting ; Fe₂O₃ ; WO₃
• 刊名：Solar Energy
• 出版年：2010
• 出版时间：August 2010
• 年：2010
• 卷：84
• 期：8
• 页码：1538-1544
• 全文大小：1038 K

文摘

Bilayer photoanodes were prepared onto glass substrates (FTO) in order to improve generated photocurrents using UV–vis light by water splitting process. A comparative study of photocatalytic was performed over the films surface using Fe₂O_3, WO₃ and mixture of bicomponents (Fe₂O₃:WO₃). Different types of films were prepared using Fe₂O_3, WO₃ and bicomponents (mixture) on FTO substrates. The films were grown by sol gel method with the PEG-300 as the structure-directing agent. The photo-generated of the samples were determined by measuring the currents and voltages under illumination of UV–vis light. The morphology, structure and related composition distribution of the films have been characterized by SEM, XRD and EDX respectively. Photocurrent measurements indicated surface roughness as the effective parameter in this study. The deposited surfaces by bicomponents or mixture are flat without any feature on the surface while the deposited surfaces by WO₃ appears rough surface as small round (egg-shaped particles) and cauliflower-like. The surface deposited by Fe₂O₃ show rough no as well as WO₃ surface. The deposited surfaces by WO₃ reveal the higher value of photocurrent measurement due to surface roughness. Indeed, the roughness can be effective in increasing contact surface area between film and electrolyte and diffuse reflection (light scattering effect). The solution (Fe₂O₃:WO₃) shows the low photocurrent value in compare to WO₃ and Fe₂O₃ hat it may be due to decomposition the compound at 450 ± 1 °C to iron-tungstate Fe₂(WO₄)₃.