Rapid room temperature synthesis forming pillared metal-organic frameworks with Kagomé net topology

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• 作者：Kui Zhou^b ; Somboon Chaemchuen^a ; Zhaoxuan Wu^b ; Francis Verpoort^a ; ^b ; ^c ; ^d ; ^{Francis@whut.edu.cn} ; ^{Francis.verpoort@ugent.be}
• 关键词：Metal-organic frameworks ; Room temperature synthesis ; Kagomé ; net ; Square grid net ; Pillared structure ; Selective adsorption
• 刊名：Microporous and Mesoporous Materials
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：239
• 期：Complete
• 页码：28-33
• 全文大小：1272 K
• 卷排序：239

文摘

Straight and energy efficient synthesis of mixed ligand MOFs under mild conditions generating Kagomé pillar net frameworks. Unified synthesis of Kagomé pillared net frameworks using a variance of metal clusters in M2(bdc)2(dabco) (M = Zn, Ni, Co). The metal cluster species in M2(bdc)2(dabco) determine the physical properties of the 3D pillared structures. The advantage of the room temperature procedure is the low cost and easy accessibility of the MOFs synthesis.