Construction of cis-azadecalone units via novel intermolecular Diels–Alder reaction
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- 作者：Dhimane ; Hamid ; Meunier ; Sté ; phane ; Vanucci-Bacqué ; Corinne ; Lhommet ; Gé ; rard
- 关键词：dihydropyridone ; cyclocondensation ; stereoselective ; Lewis acid ; octahydroquinoline
- 刊名：Tetrahedron Letters
- 出版年：2002
- 出版时间：February 25, 2002
- 年：2002
- 卷：43
- 期：9
- 页码：1645-1648
- 全文大小：157 K
文摘
N-Methoxycarbonyl-5-ethoxycarbonyl-2,3-dihydropyridin-4-one 1 reacts under thermal or Lewis acid-catalysed conditions with trimethylsilyloxybutadienes to give cis-azadecalones via a formal [4+2] cycloaddition.