Cleavable polybutadiene rubber: A versatile precursor to hydroxyl-terminated or multi-hydroxyl polybutadiene and polyethylene

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• 作者：Qinzhuo Zhou ; Anqi Wang ; Lu Dai ; Suyun Jie ; ^{jiesy@zju.edu.cn} ; Bo-Geng Li ; ^{bgli@zju.edu.cn}
• 关键词：Cis-polybutadiene rubber ; Polyethylene ; Hydroxyl ; Functionalized
• 刊名：Polymer
• 出版年：2016
• 出版时间：19 December 2016
• 年：2016
• 卷：107
• 期：Complete
• 页码：306-315
• 全文大小：2304 K
• 卷排序：107

文摘

MHPB with α,ω- and controllable intrachain hydroxyl groups was synthesized. Hydroxyl functionalized polyethylenes (HTPE, FHTPE and MHPE) were synthesized. Linear HTPE has high degree of crystallinity (70%) and melting temperature (123.2 °C). MHPE has lower degree of crystallinity (47%) and melting temperature (110.9 °C).