Unpredictable reaction of phenyltrichlorosilane with tert-butyllithium
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- 作者：Stefan Scholz ; Inge Sä ; nger ; Frauke Schö ; del ; Michael Bolte ; Hans-Wolfram Lerner ; lerner@chemie.uni-frankfurt.de" class="auth_mail
- 关键词：tert-Butyllithium ; Silanes ; Silenes ; X-ray structure analysis
- 刊名：Inorganic Chemistry Communications
- 出版年：June 2014
- 年：2014
- 卷：44
- 期：Complete
- 页码：50-52
- 全文大小：324 K
文摘
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Treatment of PhSiCl3 with 4 eq. of Li[tBu] yields tBu2(tBuC6H4CMe2CH2)SiH at 98 °C.
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At r. t. tBuPhSiCl2 was solely formed by this reaction.
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tBu2(tBuC6H4CMe2CH2)SiH crystallizes in the monoclinic space group P21/c.