Stereospecific isomerization of 2-(1-bromoalkyl)-1-sulfonylaziridines using magnesium bromide

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• 作者：Michinori Karikomi ; Takeshi Takayama ; Kazuo Haga and Kazuhisa Hiratani
• 关键词：Aziridines ; Rearrangement ; Isomerization ; Stereoselective ; Magnesium bromide
• 刊名：Tetrahedron Letters
• 出版年：2005
• 出版时间：2005
• 年：2005
• 卷：46
• 期：38
• 页码：6541-6544
• 全文大小：109 K

文摘

Novel stereospecific isomerization of 2-(1-bromoalkyl)-1-sulfonylaziridines into 2-(bromomethyl)-3-alkyl-1-sulfonylaziridines using magnesium bromide is described. The suitable choice of solvent led to good yields and diastereoselectivites.