文摘
Sulfide is a corrodant for the copper canister in the planned spent fuel repository in Finland and Sweden. Sulfide fluxes and canister corrosion rates in the clay barrier have been assessed by a reactive transport model using the geochemical simulator PFLOTRAN. These rates are linked to the dissolution of gypsum, present in the clay backfill, and the fluxes of sulfate, organic carbon and Fe(II) into interface zones where microbial activity occurs. The permeability of the rock adjacent to the clay backfill exerts a strong control on the biogeochemical processes and the resulting copper corrosion rates.