Diffusion coupling in multiply associating electrolyte solutions
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- 作者：Jean-Pierre Simonina ; jpsimonin@gmail.com" class="auth_mail" title="E-mail the corresponding author ; José ; Miguel Ramosb ; José ; Torres-Arenasb
- 关键词：Electrolytes ; Association ; non-ideal ; Diffusion ; Mean-spherical approximation (MSA)
- 刊名：Journal of Molecular Liquids
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：215
- 期：Complete
- 页码：69-76
- 全文大小：431 K
文摘
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Transient diffusion profiles of zinc(II) ion in the electric field created by major LiCl salt were obtained.
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The process is modeled by accounting for the various effects in play.
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Multiple complexation of zinc by chloride ion, non-ideality and electric field are the dominant effects.
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Deviations from ideality are described within the MSA model.