Mixed-valence μ3-oxo-centered triruthenium cluster [Ru3(II,III,III)(μ3-O)(μ-CH3CO2)6(H2O)3]·2H2O: Synthesis, structural characterization, valence-state delocalization and catalytic behavior
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- 作者：Alla Dikhtiarenko ; alla.dikhtiarenko@gmail.com" class="auth_mail" title="E-mail the corresponding author ; Sergei Khainakov ; José ; R. Garcí ; a ; José ; Gimeno
- 关键词：Triruthenium oxo-cluster ; Mixed-valence delocalization ; Synthesis ; Hydration of nitriles ; Isomerization of allylic alcohols ; Catalysis
- 刊名：Inorganica Chimica Acta
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：454
- 期：Complete
- 页码：107-116
- 全文大小：6363 K
文摘
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The trinuclear ruthenium-oxo cluster was prepared under hydrothermal conditions.
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The crystal structure was determined basing on single-crystal X-ray diffraction data.
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Trinuclear ruthenium-oxo array exhibits the trapped-valence state delocalization at room temperature.
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The complex reveals to be active catalyst for hydration of nitriles and isomerization of allylic alcohols reactions.