AC conductivity, electric modulus analysis and electrical conduction mechanism of RbFeP2O7 ceramic compound
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- 作者：S. Nasri ; nasri.saber.1@gmail.com" class="auth_mail" title="E-mail the corresponding author ; A. Oueslati ; I. Chaabane ; M. Gargouri
- 关键词：Impedance spectroscopy ; Electric modulus ; AC conductivity ; Polaron
- 刊名：Ceramics International
- 出版年：2016
- 出版时间：September 2016
- 年：2016
- 卷：42
- 期：12
- 页码：14041-14048
- 全文大小：2517 K
文摘
In this work, the diphosphate compound, RbFeP2O7, was prepared by the conventional solid-state reaction. The X-ray diffraction pattern revealed that the sample presents a single phase, that crystallizes in the monoclinic structure with a P21/C space group. Impedance analysis was performed using the equivalent circuit model, and, it indicated the presence of intra- and inter-granular contribution. Furthermore, the electrical conductivity, the dielectric properties and the relaxation behavior of this material were studied in detail using the impedance spectroscopy technique, in a frequency ranging from 200 Hz to 5 MHz at several temperatures. The temperature dependency of frequency exponent 's' shows that the correlated barrier-hopping model (CBH) is the most responsible mechanism for AC conduction in the investigated compound. In terms of CBH model, the values of maximum barrier s height, the hopping distance and the density of localized states are determined and discussed. A correlation between electrical and structural properties was also discussed.