Pseudolattice Theory of electrolyte solutions: Consistency analysis of the Quasi-Random Lattice model at infinite dilution
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- 作者：Elsa Moggia elsa.moggia@unige.it" class="auth_mail" title="E-mail the corresponding author elsa@biosafetyengineering.it" class="auth_mail" title="E-mail the corresponding author
- 关键词：Pseudolattice Theory ; Effective-carrier atmosphere ; Ionic atmosphere ; Debye-Hü ; ckel Limiting Law ; Mean activity coefficient
- 刊名：Fluid Phase Equilibria
- 出版年：2016
- 出版时间：15 November 2016
- 年：2016
- 卷：427
- 期：Complete
- 页码：231-245
- 全文大小：2164 K
文摘
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The modern Pseudolattice Theory for electrolyte solutions is discussed.
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Theoretical drawbacks are due to independence of models from the Debye-Hückel frame.
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The QRL approach is considered and convergence to the DHLL is shown.
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The discussion throws a new light on the pseudolattice treatment of ionic solutions.
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QRL formalism allows for advancing toward a unified pseudolattice approach.