Ultra-High Molecular Weights via Aqueous Reversible-Deactivation Radical Polymerization

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• 作者：R. Nicholas Carmean¹ ; Troy E. Becker¹ ; Michael B. Sims¹ ; Brent S. Sumerlin¹ ; ² ; ^{sumerlin@chem.ufl.edu}
• 关键词：photoiniferter ; RAFT ; controlled radical polymerization ; water-soluble polymers ; ultra-high-molecular-weight polymers
• 刊名：Chem
• 出版年：2017
• 出版时间：12 January 2017
• 年：2017
• 卷：2
• 期：1
• 页码：93-101
• 全文大小：1791 K
• 卷排序：2

文摘

Aqueous, catalyst-free route leads to polymers with unprecedented chain lengths Polymerization control is mediated by mild UV or sunlight irradiation Synthesis of UHMW block copolymers could facilitate access to new advanced materials