Mechanisms of the water-gas shift reaction catalyzed by carbonyl complexes M(CO)6 (M = Mo, W)
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- 作者：Ling Guo ; gl-guoling@163.com" class="auth_mail" title="E-mail the corresponding author ; Zhaoru Cao ; Naying Liu ; Xiaoyu An ; Aixia Li ; Wenli Li ; Xiaoli Zheng
- 关键词：Energetic span ; Water&ndash ; gas shift reaction ; Molybdenum and tungsten carbonyl complexes
- 刊名：International Journal of Hydrogen Energy
- 出版年：2016
- 出版时间：30 January 2016
- 年：2016
- 卷：41
- 期：4
- 页码：2432-2446
- 全文大小：1754 K
文摘
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Mechanisms of gas-phase carbonyl complexes M(CO)6 and M2(CO)10 (M = Mo, W) catalyzed WGSR are reported.
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The energetic span model is applied to reveal the kinetic behavior of the catalytic cycles.
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W2(CO)10 is considered as the most efficient catalyst of our research for WGSR.
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εd − EF value is useful as a qualitative activity descriptor in catalysis of WGSR.