Selective synthesis of fluoroalkyl-containing multisubstituted benzenes through Co-mediated [2+2+2] cycloaddition reaction with fluoroalkylated alkynes
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- 作者：Yukiho Sakaguchi ; Yoshitomo Nakazaki ; Kazuki Moriyasu ; Tsutomu Konno ; konno@kit.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：[2+2+2] Cycloaddition reaction ; Dicobalt octacarbonyl ; Fluoroalkylated alkynes ; Alkyne&ndash ; cobalt complex ; Multisubstituted benzenes
- 刊名：Journal of Fluorine Chemistry
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：179
- 期：Complete
- 页码：64-70
- 全文大小：1356 K
文摘
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Fluoroalkylated alkynes underwent a smooth Co-mediated [2+2+2] cycloaddition reaction.
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This reaction gave monofluoroalkylated multisubstituted benzenes as a sole product.
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Various fluoroalkylated alkynes could be successfully applied for this reaction.