Methane steam reforming rates over Pt, Rh and Ni(111) accounting for H tunneling and for metal lattice vibrations

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• 作者：Ernst D. German ; ^{ernst_german@yahoo.com} ; Moshe Sheintuch
• 关键词：Microkinetic modeling ; Steam reforming ; H-tunneling
• 刊名：Surface Science
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：656
• 期：Complete
• 页码：126-139
• 全文大小：1338 K
• 卷排序：656

文摘

Calculations of the rate constants for MSR over Rh(111) and Pt(111) surfaces accounting for H tunneling Numerical simulations of microkinetic models for steady-state regime Comparison of operation condition effects on the MSR rates over Rh(111), Pt(111) and Ni(111) Activity order of the catalysts and discriminating parameter