Optimization of anode material composed of Y-doped SrTiO₃ and metal and/or oxide additives for solid oxide fuel cells

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• 作者：Pramote Puengjinda ; Hiroki Muroyama ; Toshiaki Matsui ; Koichi Eguchi ; ^{eguchi@scl.kyoto-u.ac.jp}
• 关键词：Solid oxide fuel cells ; Ceramic anodes ; Catalyst impregnation ; Carbon tolerance
• 刊名：Journal of Power Sources
• 出版年：2012
• 出版时间：15 April, 2012
• 年：2012
• 卷：204
• 期：Complete
• 页码：67-73
• 全文大小：1311 K

文摘

Y-doped SrTiO₃ (YST) is currently used as an effective anode component to solve the shortcomings of conventional Ni-based cermet anodes. In this study, YST-based composite with a different ceramic oxide including samaria-doped ceria (SDC) or yttria-stabilized zirconia (YSZ) was developed as an anode material to evaluate the electrocatalytic performance in hydrogen and methane fuels. The composites showed a good potential in electrical conductivity and compatibility with YSZ electrolyte in the anodic condition. The cell with YST-SDC anode attained the better performance than that with YST-YSZ anode, which was ascribable to the high electrical conductivity and electrocatalytic activity of SDC towards the oxidation of fuels. Addition of nickel remarkably enhanced the electrochemical performance and the stability of the anodes. With 10 wt % of nickel oxide loading, the performance was significantly increased under the operation in humidified hydrogen and methane. Note that in methane fuel, the performance deterioration has not been observed over the short-term operation for 20 h.