Characterization of mechanically alloyed nanocomposites in TiO2-B2O3-Mg-C quaternary system
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- 作者：Touraj Adhami ; Bahman Nasiri-Tabrizi ; nasiri-tabrizi@pmt.iaun.ac.ir" class="auth_mail ; bahman_nasiri@hotmail.com" class="auth_mail ; Reza Ebrahimi-Kahrizsangi
- 关键词：Mechanochemical ; TiO2&ndash ; B2O3&ndash ; Mg&ndash ; C ; Nanocomposite ; Reaction mechanism ; MSR
- 刊名：International Journal of Refractory Metals and Hard Materials
- 出版年：March, 2014
- 年：2014
- 卷：43
- 期：Complete
- 页码：227-235
- 全文大小：2750 K
文摘
The influence of the simultaneous presence of magnesium and graphite on mechanosynthesis of various nanocomposite powders in TiO2-B2O3-Mg-C quaternary system was investigated. A mixture of boron oxide and titanium dioxide powders along with different amounts of magnesium and graphite was milled using a high-energy planetary ball mill to provide necessary conditions for the occurrence of a mechanically induced self-sustaining reaction (MSR). In the absence of C (100 wt.% Mg), TiB2 nanopowder was formed as a result of combustion reaction after 34 min of milling. In the presence of both Mg and C, the mechanochemical reaction was completed after different milling times depending on the weight fraction of the reducing agents in the powder mixture. In the presence of x wt.% Mg-y wt.% C (x = 85 and 90; y = 100 鈭?#xA0;x), the mechanosynthesized composites contained TiB2 and TiC as major compounds as well as MgO and Mg3B2O6 as unwanted phases. With further increasing the graphite content to 30 wt.%, no mechanical activation was observed after 90 min of milling. The nanocomposite powders showed a bimodal particle size distribution characterized by the presence of several coarse particles (鈮?#xA0;250 nm) along with finer particles with a mean size of about 75 nm. Formation mechanism of nanocomposites was explained through the analysis of the relevant sub-reactions.