Experimentally determined biomediated Sr partition coefficient for dolomite: Significance and implication for natural dolomite

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• 作者：Mó ; nica Sá ; nchez-Romá ; n^a ; ^b ; ^c ; ^{msanz78@gmail.com} ; Judith A. McKenzie^a ; Angela de Luca Rebello Wagener^d ; Christopher S. Romanek^b ; ^e ; Antonio Sá ; nchez-Navas^f ; Crisó ; gono Vasconcelos^a
• 刊名：Geochimica et Cosmochimica Acta
• 出版年：2011
• 出版时间：1 February 2011
• 年：2011
• 卷：75
• 期：3
• 页码：887-904
• 全文大小：1070 K

文摘

Two strains of moderately halophilic bacteria were grown in aerobic culture experiments containing gel medium to determine the Sr partition coefficient between dolomite and the medium from which it precipitates at 15 to 45 °C. The results demonstrate that Sr incorporation in dolomite does occur not by the substitution of Ca, but rather by Mg. They also suggest that Sr partitioning between the culture medium and the minerals is better described by the Nernst equation (D_Sr^dol = Sr_dol/Sr_bmi), instead of the Henderson and Kracek equation (D_Sr^dol = (Sr/Ca)_dol/(Sr/Ca)_solution. The maximum value for D_Sr^dol occurs at 15 °C in cultures with and without sulfate, while the minimum values occur at 35 °C, where the bacteria exhibit optimal growth. For experiments at 25, 35 and 45 °C, we observed that D_Sr^dol values are greater in cultures with sulfate than in cultures without sulfate, whereas D_Sr^dol values are smaller in cultures with sulfate than in cultures without sulfate at 15 °C.

Together, our observations suggest that D_Sr^dol is apparently related to microbial activity, temperature and sulfate concentration, regardless of the convention used to assess the D_Sr^dol. These results have implications for the interpretation of depositional environments of ancient dolomite. The results of our culture experiments show that higher Sr concentrations in ancient dolomite could reflect microbial mediated primary precipitation. In contrast, previous interpretations concluded that high Sr concentrations in ancient dolomites are an indication of secondary replacement of aragonite, which incorporates high Sr concentrations in its crystal lattice, reflecting a diagenetic process.