Neutral heterometallic cluster containing ketenylidene ligand: [Cp*Mo(CO)2(μ-H)Ru2(CO)6(μ3-ɳ1-CCO)] (Cp* = ɳ5-C5Me5)
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- 作者：Rongala Ramalakshmia ; Bijan Mondala ; Moulika Bhattacharyyaa ; Babu Vargheseb ; Sundargopal Ghosha ; sghosh@iitm.ac.in" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ketenylidene ; Semi-interstitial boride ; Molybdenum ; Ruthenium ; Mixed metals
- 刊名：Journal of Organometallic Chemistry
- 出版年：2015
- 出版时间：1 December 2015
- 年：2015
- 卷：798
- 期：part_P1
- 页码：106-111
- 全文大小：712 K
文摘
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Synthesis of heterometallic ketenylidene cluster has been described from arachno-1.
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Structural detail of the semi-interstitial boride cluster has been described.
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The electronic nature of compound 2 has been demonstrated on the grounds of DFT.