Demonstration of the branching ratio inversion for the electron attachment to phosphoryl chloride POCl3 in the gas phase between 300 and 200 K
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- 作者：Sophie Carlesa ; sophie.carles@univ-rennes1.fr" class="auth_mail" title="E-mail the corresponding author ; Ghassen Saidania ; Jean-Luc Le Garreca ; Ngary Guena ; James B.A. Mitchella ; Albert A. Viggianob ; Nicholas S. Shumanb
- 刊名：Chemical Physics Letters
- 出版年：2016
- 出版时间：16 April 2016
- 年：2016
- 卷：650
- 期：Complete
- 页码：144-147
- 全文大小：991 K
文摘
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Charged products from electron attachment reaction on POCl3 in gas phase are observed by mass spectrometry.
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Temperature dependence of the corresponding exit channels is studied down to 47.7 K.
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A kinetic model is used to fit the experimental data.