Effect of nanoconfinement on kinetics and microstructure of poly(butyl acrylate) synthesized by microemulsion polymerization
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- 作者：Nicholas Ballard ; Miren Aguirre ; José ; M. Asua ; jm.asua@ehu.es" class="auth_mail" title="E-mail the corresponding author
- 关键词：Acrylates ; Microemulsion polymerization ; Radical polymerization ; Polymer microstructure ; Kinetic modeling
- 刊名：Chemical Engineering Journal
- 出版年：2016
- 出版时间：15 November 2016
- 年：2016
- 卷：304
- 期：Complete
- 页码：667-678
- 全文大小：1789 K
文摘
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Microemulsion polymerization of butyl acrylate is affected by transfer to polymer.
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Intramolecular transfer leads to unique reaction kinetics and branched polymer.
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Intermolecular transfer leads to linking of chains within each particle.
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Molecular weight is limited by small particle size.
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Independent control of branching and molecular weight is possible.