Application of the general theory of disperse deposits formation in an investigation of mechanism of zinc electrodeposition from the alkaline electrolytes

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• 作者：Neboj&scaron ; a D. Nikolić^a ; ^{nnikolic@tmf.bg.ac.rs} ; Predrag M. Živković^b ; Jelena D. Lović^a ; Goran Branković^c
• 关键词：Electrodeposition ; Zinc ; Mechanism ; Filaments ; Dendrite ; Boulders ; Scanning electron microscope (SEM)
• 刊名：Journal of Electroanalytical Chemistry
• 出版年：2017
• 出版时间：15 January 2017
• 年：2017
• 卷：785
• 期：Complete
• 页码：65-74
• 全文大小：1774 K
• 卷排序：785

文摘

Zinc is electrodeposited potentiostatically from the zincate electrolytes. The polarization characteristics of Zn were correlated with the surface morphology. The exchange current density for Zn was estimated in the range 18.4–88 mA cm− 2. A new insight in mechanism of Zn electrodeposition is presented. The general theory of disperse deposits formation is used to obtain a new insight.