Ruthenium(II) complexes incorporating salicylaldiminato-functionalized N-heterocyclic carbene ligands as efficient and versatile catalysts for hydration of organonitriles
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- 作者：Muthukumaran Nirmala ; Gandhi Saranya ; Periasamy Viswanathamurthi<sup> ; sup><sup>viswanathamurthi72@gmail.com" class="auth_mail" title="E-mail the corresponding authorsup>
- 关键词：Salicylaldiminato-functionalized NHC ligands ; Wingtip substituents ; [Ru&ndash ; NHC] complexes ; Hydration of nitriles ; Recyclable catalyst
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 March 2016
- 年：2016
- 卷：442
- 期：Complete
- 页码：134-144
- 全文大小：4287 K
文摘
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New Ru(II) complexes containing salicylaldiminato functionalized mixed N-heterocyclic carbene (NHC) ligands have been synthesized and characterized.
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Analytical and spectral data confirm the structure of the new complexes.
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The resulting complexes have been evaluated as potential catalysts for hydration of nitriles.