4-Nitrocatecholato iron(III) complexes of 2-aminomethyl pyridine-based bis(phenol) amine as structural models for catechol-bound 3,4-PCD
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- 作者：Elham Safaeia ; b ; safaei@shirazu.ac.ir" class="auth_mail" title="E-mail the corresponding author ; Sima Heidarib ; Andrzej Wojtczakc ; Patricia Cotičd ; Anna Kozakiewiczc
- 关键词：Model complex ; Catechol dioxygenases ; Enzyme-substrate adduct ; Protocatechuate 3 ; 4-dioxygenase ; 3 ; 4-PCD
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 February 2016
- 年：2016
- 卷：1106
- 期：Complete
- 页码：30-36
- 全文大小：1207 K
文摘
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We have synthesized catecholatoto iron(III) complexes of pyridine-based aminophenol ligands.
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Complexes displayed paramagnetic properties.
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Complexes are good structural models of catechol-enzyme adduct.
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Electrochemical redox of these complexes was investigated.