Deoxygenation of octanoic acid catalyzed by hollow spherical Ni/ZrO₂

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• 作者：Hao Chen^a ; Yulong Wu^b ; ^{wylong@tsinghua.edu.cn} ; Suitao Qi^a ; ^{suitaoqi@mail.xjtu.edu.cn} ; Yu Chen^b ; Mingde Yang^b
• 关键词：Hollow spherical Ni/ZrO2 catalyst ; Deoxygenation of biooil ; Octanoic acid ; Density functional theory ; Reaction mechanism
• 刊名：Applied Catalysis A: General
• 出版年：2017
• 出版时间：5 January 2017
• 年：2017
• 卷：529
• 期：Complete
• 页码：79-90
• 全文大小：3841 K
• 卷排序：529

文摘

Deoxygenation of octanoic acid in oil-water system. A noval catalyst with Ni located inside of hollow spherical ZrO2 was prepared. The hollow spherical ZrO2 performs the role of nanoreactor. Complete conversion of octanoic acid deoxygenation could be achieved. The mechanism of deoxygenation for carboxyl function group was studied by DFT.