Thermal transformations of tris(2-thienyl)phosphine (PTh3) at low-valent ruthenium cluster centers: Part I. Carbon-hydrogen, carbon-phosphorus and carbon-sulfur bond activation yielding Ru3(CO)8L{μ-Th2P(C4H2S)}(μ-H) (L = CO, PTh3), Ru3(CO)7(μ-PTh
详细信息 查看全文
- 作者：Md Miaz Uddina ; Noorjahan Begumb ; Shishir Ghosha ; c ; Jagodish C. Sarkera ; Derek A. Tocherc ; Graeme Hogarthd ; Michael G. Richmonde ; Ebbe Nordlanderf ; ebbe.nordlander@chemphys.lu.se" class="auth_mail" title="E-mail the corresponding author ; Shariff E. Kabira ; skabir_ju@yahoo.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ruthenium cluster ; Functionalized phosphine ; C&ndash ; P ; C&ndash ; H ; and C&ndash ; S bond scission ; Thienyl ; X-ray diffraction ; DFT
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 June 2016
- 年：2016
- 卷：812
- 期：Complete
- 页码：197-206
- 全文大小：1516 K
文摘
- •
Thermal transformations of tris(2-thienyl)phosphine at low valent ruthenium cluster centers.
- •
C–H, C–P and C–S bond activation of coordinated tris(2-thienyl)phosphine.
- •
Synthesis and structure of tetraruthenium phosphinidine cluster.
- •
Synthesis and structure of pentaruthenium sulfide cluster.
- •
Formation of the novel μ4-η4-C4H3 ligand via sulfur extrusion from thiophene ring.