The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole]

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• 作者：George E. Kostakis^a ; ^b ; ^c ; ^{George.Kostakis@kit.edu} ; Pantelis Xydias^a ; Ebbe Nordlander^b ; John C. Plakatouras^a ; ^{iplakatu@cc.uoi.gr}
• 关键词：Copper ; [1-(4-((1H-benzo[d][1 ; 2 ; 3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1 ; 2 ; 3]triazole] ; Complex ; X-ray
• 刊名：Inorganica Chimica Acta
• 出版年：2012
• 出版时间：30 March, 2012
• 年：2012
• 卷：383
• 期：Complete
• 页码：327-331
• 全文大小：527 K

文摘

The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole] (L) with CuCl₂ in acetonitrile yields a dinuclear copper(II) complex [Cu₂Cl₄L₂]¡¤2CH₃CN (1¡¤2CH₃CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar.